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- Portraits: Lusardi: Simons: Virginia: Verona: Glue...
- Dartmouth College Photographic Records
- C₂-Symmetric Bis(phosphines) and Their Metal Complexes : Synthesis, Materials Application, and Screening Racemic Catalysts / Sanderson, Matthew David
- Chapter 1: The dimethylation of the C2-symmetric Pt-phosphido complex Pt((R,R)-Me-DuPhos)(IsPCH2PIs) (Is = 2,4,6-(iPr)3C6H2) to yield rac- and meso- [Pt((R,R)-Me-DuPhos)(IsMePCH2PMeIs)][OTf]2 represents an interesting case of the Horeau principle...
- Dartmouth Dissertations
- Graduate students at work in Professor David S. Gl...
- Dartmouth College Photographic Records
- Carbon-fluorine bond activation of iridium (III) compounds induced by acids and reducing agents.
- Organoiridium compounds -- Synthesis. ; Organofluorine compounds -- Synthesis. ; Ligands.
- Dartmouth Dissertations
- Synthesis and characterization of phosphido-coated gold nanoclusters and gold phosphido complexes.
- Gold -- Analysis. Gold compounds. Metal complexes -- Synthesis. Phosphides. Ligands.
- Chapter one: Gold(I) phosphido complexes: Synthesis, structure and reactivity . Deprotonation of the phosphine complexes Au(PHR 2 )Cl with aqueous ammonia gave the gold(I) phosphido complexes [Au(PR 2 )] n (PR 2 = PMes 2 ( 1 ), PCy 2 ( 2 ), P(t-Bu)...
- Dartmouth Dissertations
- Thermodynamic and spectroscopic studies of metalloprotein stability ligation and reactivity / by George P. Lisi III.
- Metal ions confer structural stability and reactivity to a large number of proteins that use the amino acids histidine (His) and cysteine (Cys) to form stable metal-ligand complexes. The stability of metal-His and metal-Cys interactions and their...
- Dartmouth Dissertations
- Behavioral treatment of chronic pain.
- Pain.
- Dartmouth Dissertations
- From nonmetal- and metal-chalcogen nanoclusters to chalcogenide nanotubes.
- Chalcogenides. Nanotubes. ; Nanostructured materials.
- A double-acceleration stage linear time of flight mass spectrometer (TOF MS) with Nd/YAG laser ablation cluster source was designed and constructed for cluster production, study and deposition. Cumulenic polycarbons SC n S ( n = 2-27) were...
- Dartmouth Dissertations
- I. Reactivity of electron deficient indoles toward nucleophiles, Diels-Alder reactions and dipolar cycloadditions; II. Synthesis of pyrrolo[3,4-b]indoles.
- Indole -- Synthesis. Indole -- Reactivity. Pyrroles. Diels-Alder reaction.
- Earlier in our laboratory, a facile synthesis of the 2- and 3-nitroindoles was realized. These compounds showed promise as powerful intermediates in the synthesis of novel structures and natural products. The reactivity of 2- and 3-nitroindoles...
- Dartmouth Dissertations
- On the first-order amplitude statistics of myocardial ultrasonic backscatter.
- Echocardiography -- Mathematical models. ; Backscattering -- Statistics. ; Myocardium.
- Dartmouth Dissertations
- Chemistry of P-H bonds at metal centers.
- Organophosphorus compounds -- Synthesis. ; Phosphine. ; Transition metal compounds.
- Dartmouth Dissertations
- Preparation and reactivity of perfluorobenzyl complexes of the group 9 metals (Co, Rh, Ir).
- Organometallic compounds. ; Organofluorine compounds. ; Organic compounds -- Synthesis. ; Transition metals. ; Cobalt compounds -- Synthesis. ; Rhodium compounds -- Synthesis. ; Organoiridium compounds -- Synthesis.
- Dartmouth Dissertations
- Palladium-catalyzed asymmetric phosphination: stereochemical and mechanistic studies.
- Asymmetric synthesis. ; Palladium catalysts. ; Phosphine. ; Organophosphorus compounds -- Synthesis. ; Stereochemistry.
- Chapter one: Synthesis, resolution and application of P-chirogenic phosphines. This chapter serves as a general introduction, and gives a brief overview of the synthesis, resolution and applications of chiral organophosphorus compounds. In...
- Dartmouth Dissertations
- Preparation of sterically hindered bis(secondary phosphines) : structure-selectivity relationships in Pt-catalyzed asymmetric phosphination and synthesis and structure of metal-phosphido complexes.
- Phosphorus compounds -- Synthesis. ; Metal complexes -- Synthesis. ; Phosphine. ; Phosphides. ; Platinum catalysts. ; Asymmetric synthesis. ; Gold compounds -- Synthesis.
- Dartmouth Dissertations
- Echocardiographic tissue characterization of normal, ischemic and infarcted myocardium.
- Echocardiography. ; Heart -- Diseases -- Diagnosis.
- Dartmouth Dissertations
- Catalytic asymmetric P-C bond formation with Pt-phosphido complexes.
- Organoplatinum compounds -- Synthesis. Organoplatinum compounds -- Reactivity. Organophosphorus compounds -- Synthesis. Organophosphorus compounds -- Reactivity. Asymmetric synthesis. Phosphate carbon. Platinum catalysts.
- Chapter One. Synthesis and Structure of Chiral Pt(Duphos) Terminal Phosphido Complexes. Treatment of Pt halide precursors with a secondary phosphine in the presence of the base NaOSiMe 3 gave the terminal phosphido complexes Pt(Duphos)(Ph)(PMeIs)....
- Dartmouth Dissertations
- Synthetic approaches to the azamacrolides [Part] I; Synthetic approaches to carbazoles and 2-acylindoles [Part] II.
- Alkaloids -- Synthesis. ; Allomones. ; Indole. ; Carbazone. ; Diels-Alder reaction.
- A novel synthetic route to the synthesis of 9-propyl-10-azacyclododecan-12-olide (1), a natural allomone isolated from the Mexican bean beetle pupa, is presented. The salient features of this synthetic route are a regioselective Beckmann...
- Dartmouth Dissertations
- Substrate and catalyst control in asymmetric synthesis of p-sterogenic bis(phosphines).
- Introduction. This chapter provides a brief overview of the thesis. Chapter 1: tert-butyl-diphosphabutarene - Synthesis and reactivity of a novel phosphacycle. Treatment of 1,2-bis(dichlorophosphino)benzene (12) with tert-butylmagesium chloride...
- Dartmouth Dissertations
- Electron transfer reaction in solution: initial charge separation distance distribution and its impact on free ion formation.
- Free radicals (Chemistry). ; Electron donor-acceptor complexes. ; Ions.
- In this study, the initial charge separation distance and its impact on free radical ion (FRI) formation are investigated in detail. Transient photocurrent techniques together with other spectroscopic methods were used with a series of donors and...
- Dartmouth Dissertations
- Activation of aliphatic carbon-fluorine bonds in iridium complexes.
- Organoiridium compounds -- Synthesis. ; Organofluorine compounds -- Synthesis.
- Dartmouth Dissertations
- Synthesis, structure, and reactivity of cationic palladium secondary phosphine complexes.
- Phosphine. ; Organophosphorus compounds -- Synthesis. ; Transition metal compounds. ; Complex compounds.
- Dartmouth Dissertations
- Thermodynamic and spectroscopic studies of metal binding properties of histidine-rich peptides and proteins.
- Histidine. ; Peptides -- Analysis. ; Proteins -- Analysis. ; Metal ions. ; Binding sites (Biochemistry) -- Thermodynamics. ; Macromolecules -- Spectra. ; Thermometric titration. ; Calorimetry. ; Electron paramagnetic resonance spectroscopy.
- Dartmouth Dissertations
- Synthesis and reactivity of terminal platinum(II) phosphido complexes: application to the platinum-catalyzed asymmetric hydrophosphination of acrylonitrile.
- Organoplatinum compounds -- Synthesis. ; Organoplatinum compounds -- Reactivity. ; Organophosphorus compounds -- Synthesis. ; Organophosphorus compounds -- Reactivity. ; Acrylonitrile.
- Dartmouth Dissertations
- A thermodynamic investigation of metal ions binding to metal trafficking proteins, peptides and small molecules using isothermal titration calorimetry.
- Metal ions. Binding sites (Biochemistry) -- Thermodynamics. Metalloenzymes. Cellular control mechanisms. Thermometric titration. Calorimetry.
- The chemistry of biology is complex and there is a great deal that is not understood. A fundamental understanding of biochemical reactions is important to aid in the identification of undiscovered reactions and is critical to fully appreciate the...
- Dartmouth Dissertations
- Activation of C-F bonds using transition metals by reduction and external acid.
- Fluorine compounds. Activation (Chemistry). Transition metal catalysts.
- Dartmouth Dissertations
- Predicting the thermodynamic properties of polymer melts and blends.
- Polymers -- Analysis. Polymers -- Thermomechanical properties. Polymer melting.
- The thermodynamic properties of pure polymers and polymer mixtures have been investigated using the so-called Born-Green-Yvon (BGY) lattice theory. Previous results applied pure component pressure-volume-temperature ( PVT ) data in order to...
- Dartmouth Dissertations
- Synthesis of multimetallic nanocomposite materials utilizing block copolymers.
- Block copolymers. Nanostructured materials -- Synthesis. Metallic composites -- Synthesis.
- Nanocomposite materials containing both gold and cobalt were synthesized using block copolymers as agents for controlling spatial organization of the nanoparticles. The targeted polymers are polystyrene- block -poly(alkyne-functional)styrene...
- Dartmouth Dissertations
- Metal-catalyzed asymmetric synthesis of P-stereogenic phosphines.
- Phosphine. Phosphorus compounds -- Synthesis. Platinum catalysts. Palladium catalysts. Asymmetric synthesis. Enantiomers.
- Abstract (Summary) Chapter One. Platinum-Catalyzed Asymmetric Alkylation of Bis(secondary) Phosphines. Efficient Screening and the Synthesis of an Enantiomerically Pure C 2 -Symmetric Diphosphine . Platinum-catalyzed asymmetric alkylation of...
- Dartmouth Dissertations
- Activation of carbon-fluorine bonds and carbon-hydrogen bonds with transition metal compounds.
- Organoiridium compounds -- Synthesis. Organofluorine compounds -- Synthesis. Transition metal compounds.
- Fluorine forms the strongest single bond to carbon, however, it is well established that transition metals can lengthen and weaken C-F bonds in fluorinated ligands. Described here are studies on the activation of C-F bonds in iridium compounds...
- Dartmouth Dissertations
- Synthesis and evaluation of alkoxyamine initiators for nitroxide-mediated polymerization.
- Polymerization. Amines -- Synthesis. Nitroxides. Radicals (Chemistry)
- Since alkoxyamines, O-alkylated nitroxide derivatives, are important control agents for nitroxide-mediated polymerization, protocols for their synthesis should be straigh- forward, cost-effective, and versatile. We have utilized a facile method for...
- Dartmouth Dissertations
- Cu(I)-catalyzed P-C bond formation and the synthesis of C₃- and C₁-symmetric p-stereogenic triphosphine ligands / by Matthew F. Cain.
- Cell cycle -- Regulation.; Transcription factors.; Luciferases.; Forkhead Transcription Factors -- genetics.
- Dartmouth Dissertations
- New technologies for constructing C-C, C-N, and C-S bonds
- I. Intermolecular C-S Bond Forming Reactions The relatively small number of efficient C-S bond forming reactions in the literature prompted an investigation into the synthesis of allylic thioethers. The technology that we developed allowed us, in...
- Dartmouth Dissertations

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